Süperhidrofobik polipropilen yüzeyler
Superhydrophobic polypropylene surfaces
- Tez No: 154972
- Danışmanlar: PROF.DR. YILDIRIM ERBİL
- Tez Türü: Yüksek Lisans
- Konular: Kimya, Chemistry
- Anahtar Kelimeler: Süperhidrofobiklik, Nilüfer Etkisi, Temas Açısı, Çöktürücü, Yüzey Pürüzlülüğü, Cassie-Baxter modeli, Polipropilen
- Yıl: 2004
- Dil: Türkçe
- Üniversite: Kocaeli Üniversitesi
- Enstitü: Fen Bilimleri Enstitüsü
- Ana Bilim Dalı: Kimya Ana Bilim Dalı
- Bilim Dalı: Belirtilmemiş.
- Sayfa Sayısı: 105
Özet
SÜPERHİ DROFOBİK POLİPROPİLEN YÜZEYLER Kazım ÖZTUNALI
Özet (Çeviri)
SUPERHYDROPHOBIC POLYPROPYLENE SURFACES Kazım ÖZTUNALI KEY WORDS: Superhydrophobicity, Lotus Effect, Contact Angle, Precipitator, Surface roughness, Cassie-Baxter model, Polypropylene. ABSTRACT: Superhydrophobicity is an important subject that has been widely researched in the recently years. It was found that the surface of the lotus plant was very rough and also superhydrophobic in structure and the water drops roll over it. This behavior was called as“lotus effect”in the literature. Polypropylene is a cheap polymer which can be easily found and was tried to generate a superhydrophobic surface in mis research. In this work, the parameters mat affect the superhydrophobic surface structure produced from polypropylene were studied. The important parameters were: the polymer concentration in solution with and without precipitator, the concentration of precipitator in solution; the application temperature and addition of polyethylene into polymer solution. Superhydrophobic surfaces were synthesized by coating polypropylene from its solution onto the glass slide by a dipping method. The surface is an example of a non-uniform and very rough structure morphologically. The surface superhydrophobicity is proportional with the concentration and the precipitator ratio in solution. The surface roughness was increased by the increase of the polymer concentration and precipitator solvent in solution till the optimum values were received. When the application temperature was increased from the gelation temperature to the transparency temperature in the polymeric solution, the contact angle values were lowered. The addition of the polyethylene into the solution was reversely affected in the surface roughness. Water drop contact angles were measured by magnifying photography and the values were calculated by using some old and new methods. Also, the surface structures were photographed by optical microscopy from plan view. The area of porosity was determined directly by image analysis of optical micrographs. The contact angle results were evaluated together with the porosity area and the results supported the Cassie-Baxter model well-known in the current literature. m
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