Study of nanoclusters containing high concentrations of stabilized atoms by optical and electron spin resonance methods
Başlık çevirisi mevcut değil.
- Tez No: 402950
- Danışmanlar: DR. DAVID M. LEE, DR. VLADIMIR KHMELENKO
- Tez Türü: Doktora
- Konular: Fizik ve Fizik Mühendisliği, Physics and Physics Engineering
- Anahtar Kelimeler: Belirtilmemiş.
- Yıl: 2016
- Dil: İngilizce
- Üniversite: Texas A&M University
- Enstitü: Yurtdışı Enstitü
- Ana Bilim Dalı: Belirtilmemiş.
- Bilim Dalı: Belirtilmemiş.
- Sayfa Sayısı: 123
Özet
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Özet (Çeviri)
Impurity-helium condensates (IHCs) are a new class of non-crystalline materials formed by injecting a gas mixture consisting of helium gas and an impurity gas into super uid helium. We studied dynamics of thermoluminescence during destruction of porous structures formed by nanoclusters of nitrogen molecules containing high concentrations of stabilized nitrogen atoms. Porous structures were formed in bulk super uid helium by injection of the products of discharges in nitrogen-helium gas mixtures through the liquid helium surface. Fast recombination of nitrogen atoms during warming-up led to explosive destruction of the porous structures accompanied by bright ashes. We also investigated thermoluminescence of ensembles of molecular nitrogen nan- oclusters, containing stabilized nitrogen atoms, immersed in liquid helium. We ob- tained experimental evidence for quantum vortex induced chemical reactions for nitrogen atoms in HeII leading to the appearance of luminescence. Thermolumines- cence was also observed in HeI due to the process of nanocluster association resulting in thermal explosions of a small fraction of nanoclusters. Impurity-helium conden- sates created by injection of nitrogen atoms and molecules as well as rare gas (RG) atoms (Ne, Ar and Kr) into super uid 4He also have been studied via electron spin resonance (ESR) techniques and optical spectroscopy. Measurements of the ground- state spectroscopic parameters of nitrogen atoms show that the nanoclusters have a shell structure. N and O atoms reside in solid molecular layers of N2. These lay- ers form on the surfaces of RG (Ar or Kr) nanoclusters. We studied the dynamics of thermoluminescence spectra emitted during the warming of porous N-N2-RG-He samples inside the super uid helium. Using this experimental approach, it is possible to study chemical reactions of heavy atoms and molecules at very low temperatures where normally di usion and quantum tunneling in solid matrices not possible.
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