Koordinasyon bileşiklerinin arabasamak ve toplam kararlılık sabitlerinin potansiyometrik yöntemle tayini
Determination of stability and formation constant of metal complexes by potentiometric titration
- Tez No: 114368
- Danışmanlar: DOÇ. DR. SİNAN SAYDAM
- Tez Türü: Yüksek Lisans
- Konular: Kimya, Chemistry
- Anahtar Kelimeler: Bakır, Kararlılık sabiti, Kobalt, Kompleksler, Krom, Nikel, Potansiyometrik yöntem, Potentiometric titration^ stepwise stability constant, overall stability constant, nickel, cupper, cobalt, chrome, complex, non-linear, MathCad. Ill, Copper, Stability constant, Complexes, Chromium, Potentiometric method
- Yıl: 2001
- Dil: Türkçe
- Üniversite: Fırat Üniversitesi
- Enstitü: Fen Bilimleri Enstitüsü
- Ana Bilim Dalı: Kimya Ana Bilim Dalı
- Bilim Dalı: Belirtilmemiş.
- Sayfa Sayısı: Belirtilmemiş.
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Özet (Çeviri)
ABSTRACT DETERMINATION OF STABILITY AND FORMATION CONSTANT OF METAL COMPLEXES BY POTANTIOMETRIC TITRATION MASTER THESIS Fatma KAYA Fırat University Graduate School of Natural and Applied Science Department of Chemistery 2001,Page:53 In this work, to calculate the stepwise and overall stability constants of coordination compounds from potentiometric titration data, a computer program have been written. The computer program runs under Windows operating system and written for symbolic programming language, MathCad, which utilizes Newton-Raphson method for solving the non-linear equations. The computer program was tested with potentiometer titration data from Ni(II)glycine and Cu(II)glycine complexes. It was found that the stability constant we found from the experimental data and literatures were in good agreement with each other. After seeing that the computer program works well with the data we get from method, it was applied to the two ethanol amine complexes of Co(III) and Cr(III). The the potentiometric titration stability constants of both complexes were calculated as 1.51 and 70.5 respectively.
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