Geri Dön

Catalytic combustion of gas streams carrying organic pollutants

Başlık çevirisi mevcut değil.

  1. Tez No: 38475
  2. Yazar: M.METİN BALLIKAYA
  3. Danışmanlar: DOÇ.DR. SÜHEYDA ATALAY
  4. Tez Türü: Yüksek Lisans
  5. Konular: Fizik ve Fizik Mühendisliği, Physics and Physics Engineering
  6. Anahtar Kelimeler: Belirtilmemiş.
  7. Yıl: 1995
  8. Dil: İngilizce
  9. Üniversite: Ege Üniversitesi
  10. Enstitü: Fen Bilimleri Enstitüsü
  11. Ana Bilim Dalı: Belirtilmemiş.
  12. Bilim Dalı: Belirtilmemiş.
  13. Sayfa Sayısı: 75

Özet

Özet yok.

Özet (Çeviri)

8.0 Summary The catalytic combustion of methylenechloride, one of the chloromethanes, was investigated by developing metal oxide catalysts coated on the monolith support or on spherical alumina pellets. The prepared catalysts were tested at the different temperatures between 200 and 500°C and at varying GHSV values with an excess air of 216%. The catalyst having the composition of 15% Cr203, 5% of Ce203 and 80% y- AI2O3 on the monolith was found to be ultimate due to the complete destruction of methylenechloride and to the highest mechanical stability. The operating conditions were proposed as 77778 h"1 for the GHSV, 216% for the excess air and 400 - 500°C for the temperature range to combust completely. The kinetics of the reaction was investigated on the ultimate catalyst at differential reactor condition. The reaction rates were calculated for different oxygen and methylenechloride partial pressures. The experimental reaction rates were adapted to Mars and van Krevelen model to determine reaction orders with respect to the reactants and reaction rate constants by using a nonlinear regression technique, and the reaction rate was found as, t I, pO-2 pO.95 _ KiKorCH2Cl2r02 Kor02 + KirCH2Cl2 The activation energies determined from Arrhenius relation experimentally were 12597.5 and 4552.5 kJ/kmol, and these were in the range reported in the literature given for the similar hydrocarbons. 61

Benzer Tezler

  1. Sıcak yapay gazdan katalitik amonyak giderimi

    Catalytic ammonia removal from hot syngas

    YELİZ ÇETİN

    Doktora

    Türkçe

    Türkçe

    2017

    Kimya Mühendisliğiİstanbul Teknik Üniversitesi

    Kimya Mühendisliği Ana Bilim Dalı

    PROF. DR. HASAN CAN OKUTAN

    DOÇ. DR. ALPER SARIOĞLAN

  2. Kömürlerin kendiliğnden yanmasının teorik ve deneysel incelenmesi

    Theoretical and experimental investigations of spontonequs combustion of coals

    FEHMİ AKGÜN

    Doktora

    Türkçe

    Türkçe

    1994

    Makine Mühendisliğiİstanbul Teknik Üniversitesi

    PROF.DR. AHMET ARISOY

  3. Aşınmaya karşı plazma püskürtme ve HVOF (yüksek hızlı oksit-yakıt) püskürtme yöntemleriyle yüzey hazırlama

    Başlık çevirisi yok

    TANER BİLGE

    Yüksek Lisans

    Türkçe

    Türkçe

    1998

    Makine Mühendisliğiİstanbul Teknik Üniversitesi

    Makine Mühendisliği Ana Bilim Dalı

    PROF. DR. ADNAN DİKİCİOĞLU

  4. Experimental study of NOx conversion efficiency and BSFC for a thermally insulated SCR system

    Termal olarak izole edilmiş bir SCR sisteminin, NOx indirgeme ve özgül yakıt tüketiminin deneysel olarak incelenmesi

    FATİH TABAK

    Yüksek Lisans

    İngilizce

    İngilizce

    2010

    Makine Mühendisliğiİstanbul Teknik Üniversitesi

    Makine Mühendisliği Ana Bilim Dalı

    PROF. DR. METİN ERGENEMAN